中国给水排水2024年污水处理厂提标改造(污水处理提质增效)高级研讨会(第八届)邀请函暨征稿启事
 
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赵明 --- 北京清华大学环境学院副教授/博导 职 务: 院长助理 固体废物污染控制与资源化研究所

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核心提示:赵明 --- 北京清华大学环境学院副教授/博导 职 务: 院长助理 固体废物污染控制与资源化研究所
中国给水排水2024年污水处理厂提标改造(污水处理提质增效)高级研讨会(第八届)邀请函暨征稿启事

中国给水排水2024年污水处理厂提标改造(污水处理提质增效)高级研讨会(第八届)邀请函暨征稿启事
 


 

姓       名: 赵明
所在单位: 固体废物污染控制与资源化研究所
课 题  组: 生物质能源与碳捕集转化技术实验室
职      称 : 副教授/博导 
职       务: 院长助理
通讯地址: 北京清华大学环境学院, 100084
办公地点: 中意环境节能楼814/华业大厦2504
办公电话: 010-62784701/62789293
传       真: 010-62784701
电子邮箱: ming.zhao@tsinghua.edu.cn

 

 

 

教育背景

1997.9 – 2001.6      南开大学    环境科学与工程学院    环境化学学士

2003.9 – 2006.6      清华大学    环境科学与工程系    环境工程硕士

2006.7 – 2010.8      悉尼大学    化学与分子生物工程系    化学工程博士

工作履历

2015.06 – 今                清华大学    环境学院    副教授、博导 

2014.07 – 2015.06      清华大学    环境学院    副教授

2014.01 – 2014.06      帝国理工学院    化学工程系    Research Fellow

2012.11 – 2013.12      利兹大学    过程、环境与材料工程学院    Research Fellow

2011.10 – 2012.10      悉尼大学/帝国理工学院    Principle Investigator/Coordinator of Joint Project

2010.10 – 2011.10      悉尼大学    可持续技术实验室    Postdoctoral Research Associate

教学

1、 主讲本科生春季课程《低碳技术与管理》全英文32学时(40050752)

2、 合讲本科生秋季课程《可持续型社会:环境、能源与行为》全英文16学时(40050773,总48学时)

3、 主讲中法环境/能源项目硕士课程《二氧化碳捕集与封存技术》全英文32学时

学术兼职

1、 中国环保产业协会固体废物处理利用委员会常务副秘书长

 

3、 中国环境科学学会理事会员

4、 中国能源环保高新技术产业协会常务理事

5、 多个SCI期刊(EES, EST, ACB, IJHE, RSC Advances等)审稿人

6、 美国化学会年会(ACS National Meeting)环境化学学部会议召集人(ENVR Symposium Organizer)

7、 英国皇家化学会RSC(562711)、英国化学工程师协会IChemE(99958499)、美国化学会ACS(30104666)、美国化学工程师协会AIChE(9900048397)、英国碳捕集与封存研究中心UKCCSRC、国际能源署温室气体研发计划IEAGHG、澳大利亚工程师协会EA(3921770)、澳大利亚能源协会AIE(3448)等会员

研究领域

1、 生物质废物热化学能源化技术

生物质废物可燃分高,而且碳中性,是可再生的低碳能源。但生物质废物含水率高、成分复杂,实现其能源化亟需高效低耗新技术的支撑。我课题组开发以BECCS(Biomass Energy with CCS)为核心概念的热化学技术,碳中性的生物质(废物)在转化为富氢或纯氢燃气的同时,实施原位碳捕集,提高了生物质废物能源化的品质,同时实现大气CO2的负排放。

具体研究方向方向包括:高效预处理技术、污泥-木质废物二元共气化、催化-吸附双重加强生物质气化制富氢燃气、化学链自氧化催化重整、循环型碱热处理生物质废物制氢、热化学过程污染物识别与控制技术等。
涉及专业知识:固废资源化工程、化学反应工程、材料科学与工程、热能工程。

2、 可持续型二氧化碳捕集技术

CO2是最重要的人为源温室气体,碳捕集技术为削减CO2排放提供了可行的方案。化学吸收(如胺淋洗、钙基吸收等)捕集效率高,但解吸耗能过大、吸收剂循环性能较差;物理吸附虽然脱附再生便利,但吸附剂成本高、捕集效率差。我课题组主要针对以上问题,开发低成本、高效率、高循环性能、低能耗的可持续的CO2捕集技术,主要以钙基、镁基、碱金属锆酸盐/正硅酸盐等中高温度段固体吸收剂为主。
涉及专业知识:化学反应工程、材料科学与工程、化工热力学、热能工程等。

3、 二氧化碳利用与转化技术

碳捕集过程聚集大量高纯度CO2,但地质封存技术尚不能满足商业化需求,且受到邻避效应制约。开发大规模CO2的利用与转化技术可解决这一难题。我课题组重点开发的技术包括:高浓度下的微藻捕碳技术、微藻能源化技术、超临界CO2应用技术、CO2干式重整技术、CO2催化还原高级过程等等。
涉及专业知识:环境工程、藻类学、生物燃料技术、化学反应工程、材料科学与工程、催化科学等。

课题组成员:

1、 姬国钊:博士后(入选2016清华大学国际博士后交流计划A类),入站前获得澳大利亚昆士兰大学(University of Queensland)化学工程博士学位,研究领域为高温下工业气体分离过程的数值模拟与试验研究等。目前在站从事生物质废物热化学过程以及CCS过程中气体分离技术的研究;

2、 范怡然:博士后(入选2017清华大学国际博士后交流计划A类),入站前获得英国帝国理工学院(Imperial College London)环境工程博士学位,研究领域为生物质废物热解资源化技术。

3、 Zaki Memon 梅在天:2014级普博生(巴基斯坦),从事碱金属锆酸盐应用于吸附加强的生物质催化重整技术研究;

4、 Arun Vuppaladadiyam 吴克利:2015级普博生(印度),从事钙循环碳捕集与可再生能源(微藻)耦合的高级碳捕集技术;

5、 王凡: 2016级直博生,本科毕业于北京林业大学环境工程专业,目前从事生物质废物气化的高级材料与过程工程研究;

6、 Abdul Raheem 单良:博士生(2016级巴基斯坦),从事微藻类生物质热化学转化研究;

7、崔晓敏:2017级普博生,西安交通大学环境工程硕士毕业。目前从事生物质废物热化学转化技术研究;

8、王伟:2018级普博生,北京林业大学环境工程硕士毕业。从事CO2催化转化技术研究;

9、吕熠:2018级普博生,武汉大学环境工程硕士。从事污泥热化学处理技术研究;

10、宋银强:2015级硕士生,武汉大学本科毕业。从事钙基CO2吸收剂稳定化与反应器研究;

11、何煦:2016级硕士生,本科毕业于清华大学环境学院,目前从事高级钙基碳吸收材料的研究;

12、Wafa Dastyar 钟诚:2016级硕士生(伊朗),从事有机固废资源化的高级预处理以及全过程污染控制研究;

13、张晨光:2017级硕士生,中国农业大学本科毕业,目前从事生物质废物高端资源化技术研究;

14、陈兆佳:2017级硕士生(马来西亚),本科毕业于清华大学环境学院,从事离子液体用于CO2捕集与生物质预处理的研究;

15、杨航:2017级工硕(深研院),本科毕业于清华大学环境学院,从事污泥热处理技术与设备研究;

16、邹书娟:2018级硕士生,本科就读于清华大学环境学院,从事生物质催化气化研究。

(课题组长期招收本科生、研究生及博士后,请发CV至ming.zhao@tsinghua.edu.cn)

GROUP ALUMNI:

赵枭:美国奥本大学(Auburn University)环境工程博士学位。2015年10月-2017年10月博士后在站。目前为中国农业大学水利与土木工程学院副教授,入选2017年中国农业大学“优秀人才”。个人网页:http://water.cau.edu.cn/art/2017/11/24/art_2124_545124.html

卓昊然:清华大学环境学院2016级本科毕设学生。毕业去向:耶鲁大学攻读硕士学位。

许肖尹:清华大学环境学院2017级本科毕设学生。毕业去向:墨尔本大学攻读化学工程博士学位(全奖)。

 

研究概况


 

2、 清华大学自主科研计划学科交叉专项“城市污泥与木质废物共气化处理技术的研究”,2016-2018,项目负责人;

3、 国家自然科学基金青年基金项目“高循环性能钙基吸收剂用于烟气CO2捕集与联合水泥生产的基础研究”,2016-2018,项目负责人;

4、 清华大学自主科研计划重点基础研究课题“基于钙硅基工业固废的碳捕集材料开发及其应用基础研究”,2015-2017,联合申请人;

5、 绿色经济与可持续发展中心项目,课题二“区域土壤污染及综合控制策略研究”,2015-2018,课题负责人;

6、 环境学院青年教师支持经费,2014-2016,经费负责人;

7、 北京市优秀人才资助项目“二氧化碳捕集联合水泥生产技术”,2015-2017,项目负责人;

8、 环境学院开放基金项目“高硅钙废物用于碳捕集-水泥联产技术的研究”,2015-2017,项目负责人;

9、 教育部留学回国基金项目“工业废渣源多晶态材料用于钙基二氧化碳吸收剂抗烧结失活的机理研究”,2015-2017,项目负责人;

10、 清华大学骨干人才支持基金,2014,经费负责人

奖励与荣誉


 

2、 入选北京市优秀人才计划,2014

3、 入选“清华大学骨干人才支持计划”,2014

4、 入选教育部“春晖计划”,2012

5、 第八届清华大学 – 横山亮次优秀论文,2011

6、 首届澳大利亚十大杰出华人青年(金合欢奖)– 专业学术界获奖人,2011

7、 澳大利亚能源协会优秀博士论文,2010

8、 CSC-USYD全额博士奖学金,2006-2010

学术成果

一作及通讯(*通讯作者):


2018 (Sum IF=39.251 so far):


1.Guozhao Ji, Ming Zhao,* and Geoff Wang. Computational fluid dynamic simulation of a sorption-enhanced palladium membrane reactor for enhancing hydrogen production from methane steam reforming. Energy, 2018, IN PRESS. DOI: 10.1016/j.energy.2018.01.092 (IF=4.259)

2.Abdul Raheem#, Arun K. Vuppaladadiyam#, Pepijn Prinsen#, Ming Zhao* and Rafael Luque*. Biofuel Production based in Microalgae: A sustainable bioenergy approach. Journal of Cleaner Production, 2018, IN PRESS. DOI: 10.1016/j.jclepro.2018.01.125. (IF=5.715)

3.Abdul Raheem, Vineet Singh Sikarwar, Jun He, Wafa Dastyar, Dionysios D. Dionysiou, Wei Wang, and Ming Zhao*. Opportunities and Challenges in Sustainable Treatment and Resource Reuse of Sewage Sludge: A Review. Chemical Engineering Journal, 2018, IN PRESS. DOI: 10.1016/j.cej.2017.12.149 (IF=6.216)

4.Arun K. Vuppaladadiyam#, Pepijn Prinsen#, Abdul Raheem#, Rafael Luque and Ming Zhao*. Microalgae cultivation and metabolites production: a comprehensive review. Biofuels, Bioproducts and Biorefining, 2018, ACCEPTED. (IF=4.52)

5.Arun K. Vuppaladadiyam#, Joseph G. Yao#, Nicholas Florin, Anthe George, Xiaoxiong Wang, Leen Labeeuw, Yuelu Jiang, Ryan W. Davis, Ali Abbas, Peter Ralph, Paul S. Fennell and Ming Zhao*. Impact of Flue Gas Compounds on Microalgae and Mechanisms for Carbon Assimilation and Utilization – A Review. ChemSusChem, 2018, 11(2), 334-355. (IF=7.226)

6.Abdul Raheem, Guozhao Ji, Asif Memon, Siva Sivasangar, Wei Wang, Ming Zhao* and Yun Hin. Taufiq-Yap. Catalytic gasification of algal biomass for hydrogen-rich gas production: Parametric optimization via central composite design. Energy Conversion and Management, 2018, 158, 235-245. (IF=5.099)

7.Zhao Xiao, Ji Guozhao, Liu Wen, He Xu, Anthony Edward J. and Zhao Ming*, Mesoporous MgO promoted with NaNO3/NaNO2 for rapid and high-capacity CO2 capture at moderate temperatures, Chemical Engineering Journal, 2018, 332, 216-226 (IF=6.216)


2017 (Sum IF=94.779):


8.Yinqiang Song# , Guozhao Ji#, Xiao Zhao, Xu He, Xiaomin Cui, Ming Zhao* , Effects of drying methods on wet chemistry synthesis of Al-stabilized CaO sorbents for cyclic CO2 capture, Energy & Fuels, 2017, 31 (11), 12521–12529 (IF=3.091)

9.Ji Guozhao#, Xu Xiaoyin#, Yang Hang, Zhao Xiao, He Xu, Zhao Ming*, Enhanced hydrogen production from sawdust decomposition using hybrid-functional Ni-CaO-Ca2SiO4 materials, Environmental Science & Technology, 2017, 51(19), 11484–11492 (IF=6.198)

10.Yanjun Liu, Wenjing Lu, Wafa Dastyar, Ruihong Meng, Yanting Liu, Xindi Fu, Hao Li, Xi Jin, Ming Zhao*, Hongtao Wang*. Fugitive halocarbon emissions from working face of municipal solid waste landfills in China as a source of greenhouse gases. Waste Management, 2017, 70, 149-157. (IF=4.03)

11.Abubakar Yusuf, Colin Snape, Jun He*, Honghui Xu, Chaojie Liu, Ming Zhao*, George Zheng Chen, Bencan Tang, Chengjun Wang, Jiawei Wang & Sailesh N. Behera. Advances on transition metal oxides catalysts for formaldehyde oxidation: A review. Catalysis Reviews: Science and Technology, 2017, 59(3), 189-233. (IF=6.143)

12.Xiao Zhao, Hui Zhou, Vineet S. Sikarwar, Ming Zhao*, Ah-Hyung A. Park*, Paul S. Fennell, Laihong Shen and Liang-Shih Fan. Biomass-based Chemical Looping Technologies: the Good, the Bad and the Future. Energy Environmental Science, 2017, 10(9), 1885-1910. Front Cover Article. (IF=29.518)

13.Vineet Singh Sikarwar#, Guozhao Ji#, Ming Zhao*, and Yujue Wang*. Equilibrium modelling of sorption enhanced co-gasification of sewage sludge and wood for hydrogen-rich gas production with in-situ carbon-dioxide capture. Industrial & Engineering Chemistry Research, 2017, 56(20), 5993-6001. (IF=2.843)

14.Vineet Singh Sikarwar, Ming Zhao*, Paul S. Fennell, Nilay Shah and Edward J. Anthony*. Progress in biofuel production from gasification. Progress in Energy & Combustion Science, 2017, 61, 189-248. (IF=17.382)

15.Faith Bamiduro, Guozhao Ji, Andy P. Brown, Valerie A. Dupont, Ming Zhao* and Steven J. Milne*. Spray-dried sodium zirconate: a rapid absorption powder for CO2 capture with enhanced cyclic stability. ChemSusChem, 2017, 10, 2059-2067. (IF=7.226)

16.Muhammad Zaki Memon, Xiao Zhao, Vineet Singh Sikarwar, Arun K. Vuppaladadiyam, Steven J. Milne, Andy P. Brown, Jinhui Li, Ming Zhao*. Alkali Metal CO2 Sorbents and the Resulting Metal Carbonates: Potential for Process Intensification of Sorption-Enhanced Steam Reforming. Environmental Science & Technology, 2017, 51(1), 12-27. (IF=6.198)

17.Guozhao Ji, Muhammad Zaki Memon, Haoran Zhuo, Ming Zhao*. Experimental study on CO2 capture mechanisms using Na2ZrO3 sorbents synthesized by soft chemistry method. Chemical Engineering Journal, 2017, 313, 646–654. (IF=6.216)

18.Abdul Raheem, Valerie Dupont, Abdul Channa, Xiao Zhao, Arun Vuppaladadiyam, Yun-Hin Taufiq-Yap, Ming Zhao*, Razif Harun*. Parametric characterisation of air gasification of chlorella vulgaris biomass. Energy & Fuels, 2017, 3, 2959?2969. (IF=3.091)

19.Muhammad Zaki Memon#, Guozhao Ji#, Jinhui Li, Ming Zhao*. Na2ZrO3 as an effective bifunctional catalyst-sorbent during cellulose pyrolysis. Industrial & Engineering Chemistry Research, 2017, 56 (12), 3223–3230. (IF=2.843)

2016 (Sum IF=36.606):

20.Vineet Singh Sikarwar, Ming Zhao*, Peter Clough, Joseph Yao, Xia Zhong, Mohammad Zaki Memon, Nilay Shah, Edward J. Anthony and Paul S. Fennell*. An overview of advances in biomass gasification. Energy & Environmental Science, 2016, 9, 2939-2977. (IF=29.518) Front Cover Article of Issue 10, Volume 9, October 2016.

21.Yanjun Liu, Yanting Liu, Hao Li, Xindi Fu, Hanwen Guo, Ruihong Meng, Wenjing Lu*, Ming Zhao*, Hongtao Wang. Health risk impacts analysis of fugitive aromatic compounds emissions from the working face of a municipal solid waste landfill in China. Environment International, 2016, 97, 15-27. (IF=7.088)


2015:


LBC group was still a baby…


2014 and before (Sum IF=100.245):


22.Ming Zhao*, Jeffrey Shi, Xia Zhong, Sicong Tian, John Blamey, Jianguo Jiang*, and Paul S. Fennell*. Novel Calcium Looping Absorbent Incorporated with Polymorphic Spacers for CO2 Capture and Hydrogen Production. Energy & Environmental Science, 2014, 7, 3291-3295; (IF=29.518)

23.Ming Zhao*, Bilton M, Brown AP, Cunliffe AM, Dupont VA, Comyn TP and Milne SJ. Durability of CaO-CaZrO3 adsorbents prepared for high-temperature CO2 capture by a wet chemical method. Energy & Fuels, 2014, 28, 1275-1283 (IF=3.091)

24.Ming Zhao*, Minett AI and Harris AT*. A review of techno-economic models for the retrofitting of conventional pulverized-coal power plants for post-combustion capture (PCC) of CO2. Energy & Environmental Science, 2013, 6, 25-40 (IF=29.518)

25.Ming Zhao*, Yang, X, Church TL and Harris AT*. Novel CaO-SiO2 sorbent and bifunctional Ni/Co-CaO/SiO2 complex for selective H2 synthesis from cellulose, Environmental Science & Technology, 2012, 46, 2976-2983 (IF=6.198)

26.Ming Zhao*, Church TL and Harris AT*. SBA-15 supported Ni-Co bimetallic catalysts for enhanced hydrogen production during cellulose decomposition, Applied Catalysis B: Environmental, 2011, 101, 522-530 (IF=9.446)

27.Ming Zhao*, Yang X, Church TL and Harris AT*. Interaction between a bimetallic Ni-Co catalyst and micrometer-sized CaO for enhanced H2 production during cellulose decomposition, International Journal of Hydrogen Energy, 2011, 36, 421-431, (IF=3.582)

28.Ming Zhao, Florin NH and Harris AT. Mesoporous supported cobalt catalysts for enhanced H2 production during cellulose decomposition, Applied Catalysis B: Environmental, 2010, 97, 142-150, (IF=9.446)

29.Ming Zhao, Florin NH and Harris AT. The influence of supported Ni catalysts on the product gas distribution and H2 yield during cellulose pyrolysis, Applied Catalysis B: Environmental, 2009, 92, 185-193 (IF=9.446)


合作文章:


1.John Blamey, Ming Zhao, Vasilije Manovic, Edward Anthony, D. R. Dugwell, Paul Fennell*. A Shrinking Core Model for Steam Hydration of CaO-Based Sorbents Cycled for CO2 Capture. Chemical Engineering Journal, 2016, 291, 298-305

2.Peter T. Clough, Matthew E. Boot-Handford, Ming Zhao, Paul S. Fennell. Degradation study of a novel polymorphic sorbent under realistic post-combustion conditions. Fuel, 2016, 86, 186, 708-713

3.Feng Yan, Jianguo Jiang*, Ming Zhao, Sicong Tian, Kaiming Li, Tianran Li. A green and scalable synthesis of highly stable Ca-based sorbents for CO2 capture. Journal of Materials Chemistry A, 2015, 3, 7966-7973

4.Feng Yan, Jianguo Jiang*, Kaimin Li, Sicong Tian, Ming Zhao and Xuejing Chen. Performance of Coal Fly Ash Stabilized, CaO-based Sorbents under Different Carbonation-Calcination Conditions. ACS Sustainable Chemistry & Engineering, 2015, 3 (9), 2092-2099

5.Das A, Choucair M, Southon PD, Mason JA, Ming Zhao, Kepert CJ, Harris AD, D'Alessandro DM. Application of the Piperazine Grafted CuBTTri Metal-Organic Framework in Postcombustion Carbon Dioxide Capture. Microporous & Mesoporous Materials, 2013, 174, 74-80

6.Yang X, Yuan L, Peterson V, Minett AI, Ming Zhao, Kirby N, Mudie S and Harris AT. Pre-treatment Control of Carbon Nanotube Array Growth for Gas Separation: Alignment and Growth Studied Using Microscopy and Small Angle X-ray Scattering. ACS Applied Materials & Interfaces, 2013, 5, 3063-70

7.Das A, Southon PD, Ming Zhao, Kepert CJ, Harris AT and D'Alessandro DM. CO2 adsorption using physisorption and chemisorption Interactions in piperazine-grafted Ni2(1,4-dioxido-2,5-benzenedicarboxylate). Dalton Transactions, 2012, 41, 11739-11744

8.Church TL, Fallani S, Liu J, Ming Zhao and Harris AT. Novel biomorphic Ni/SiC catalysts that enhance cellulose conversion to hydrogen, Catalysis Today, 2012, 190, 98-106

9.Widyaningrum RN, Church TL, Ming Zhao and Harris AT. Mesocellular foam silica-supported Ni catalyst to enhance H2 production from cellulose pyrolysis. International Journal of Hydrogen Energy, 2012, 37, 9590-9601

10.Yang Z, Ming Zhao, Florin NH and Harris AT. Synthesis and characterization of CaO nanopods for high temperature CO2 capture, Industrial & Engineering Chemistry Research, 2009, 48, 10765-10770


会议论文与口头报告:


1.Abdul Raheem, Razif Harun and Zhao Ming*. Parametric optimization of syngas production from algal biomass gasification via central composite design. 253rd American Chemical Society Meeting and Exposition, 2017, San Francisco.

2.Muhammad Zaki Memon and Ming Zhao*. Potential applications of alkali metal sorbents (Li2ZrO3, Li4SiO4 and Na2ZrO3) as bifunctional material for biomass gasification. 253rd American Chemical Society Meeting and Exposition, 2017, San Francisco.

3.Vineet S. Sikarwar and Ming Zhao*. Design of co-gasification of dried sludge and woody biomass for synthesis gas production in a fixed bed downdraft gasifier using Aspen Plus. 252nd American Chemical Society Meeting and Exposition, 2016, Philadelphia. Aug 23. 3.25 pm.

4.Xiaomin Cui, Xiao Zhao and Ming Zhao*. Efficient hydrogen production from pyrolysis of waste beech wood by applying multi-function Ni/Co-CaO/SiO2 powder in TG-MS system. 252nd American Chemical Society Meeting and Exposition, 2016, Philadelphia. Aug 24.

5.Xu He and Ming Zhao*. Novel strategy to reduce sintering, based on polymorphic materials, and application to carbon capture and storage. 252nd American Chemical Society Meeting and Exposition, 2016, Philadelphia. Aug 22. 2 pm to 4 pm.

6.Muhammad Zaki Memon, Haoron Zhuo and Ming Zhao*. Alkaline ceramic CO2 sorbents (Li2ZrO3, Li4SiO4 and Na2ZrO3) and their potentials as bifunctional materials for sorption-enhanced steam reforming processes. 252nd American Chemical Society Meeting and Exposition, 2016, Philadelphia. Aug 23. 1.50 pm.

7.Ming Zhao* and Harris AT. Novel SiO2 supported CaO sorbent and bifunctional Ni/Co-CaO/SiO2 complex for sorption-and-catalysis-enhanced H2 production from biomass. 241st National Meeting & Exposition of the American-Chemical-Society, 2011, 241, 34-Fuel;


著作章节:


1.Ji Guozhao and Ming Zhao*. Membrane Separation Technology in Carbon Capture. In Recent Advances in Carbon Capture and Storage. Ed. Yongsueng Yun. Publisher: InTech. 2017. DOI: 10.5772/62966

2.Sikarwar Vineet and Ming Zhao*. Biomass Gasification.. In Encyclopedia of Sustainable Technologies. Publisher: Elsevier. 2017. DOI: http://dx.doi.org/10.1016/B978-0-12-409548-9.10533-0

 



 
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