赵华章---北京大学环境工程系副教授_水业人物_行业资讯

赵华章

系所:	环境工程系
职称:	副教授
联系电话:	010-62754292-815
E-mail:	zhaohuazhang@iee.pku.edu.cn; zhaohuazhang@pku.edu.cn
个人主页:	http://www.iee.pku.edu.cn/klwss/index.php/Info/show/id/84 (CV_English version)

赵华章

入选教育部“新世纪优秀人才支持计划”（2010年）、北京市“科技新星计划”（2007年），获教育部科技进步一等奖等省部级奖励3项。主持国家自然科学基金、“十一五”科技支撑子课题等共10项，作为主要研究骨干参加国家863课题、国家自然科学基金等10余项。已在国内外期刊上发表论文80余篇，其中SCI收录40余篇（被SCI他引400余次，h因子12），EI收录40余篇，在环境领域顶级期刊ES&T上发表5篇。获授权专利9项。

研究领域

主要从事水质净化理论与技术、水处理过程化学、环境工程功能材料方面的教学科研工作，包括：（1）絮凝相关的饮用水和废水处理技术开发和材料研制（化学絮凝、电絮凝、零价铁等技术；新型絮凝剂、脱水剂、破乳剂、固化剂等材料）；（2）新型电极制备和基于微生物燃料电池的水处理技术开发（除砷、氟、磷、氮和还原转化CO2等）；（3）“生物－物化”组合水处理工艺开发和应用。

奖励荣誉

1. 教育部“新世纪优秀人才支持计划”，2010
2. 北京市“科技新星”计划，2007
3. “固定化微生物处理高氨氮废水的研究”，教育部科技进步奖一等奖，2007(排名第8)
4. “高效多功能有机高分子絮凝剂”，山东省科技进步三等奖，2002(排名第3)
5. “高效多功能有机高分子絮凝剂”，山东高校优秀科研成果二等奖，2001(排名第3)
6. 北京大学宝洁奖教金，2008
7. 北京大学第八届青年教师教学演示竞赛优秀奖，2009

教育背景

2003 年毕业于中科院生态环境研究中心获环境工程博士学位
2000 年毕业于山东大学环境科学与工程学院获环境工程硕士学位
1995 年毕业于中国石油大学化学与化工学院

工作经历

2007.8 至今北京大学环境科学与工程学院副教授
2005.7-2007.7 北京大学环境学院讲师
2003.8-2005.7 清华大学环境科学与工程系博士后
1995.9-1997.7 青岛华润石油化工有限公司化验室主任

科研项目

1. “十二五”国家科技支撑计划项目“城镇低碳发展关键技术集成研究与示范”课题“城镇生活垃圾处理系统低碳技术集成研究与示范”(2011BAJ07B04)之专题“生活垃圾渗滤液膜工艺浓缩液碳固化技术”，70万元，专题负责人(2011.1-2014.6)
2. 北京市朝阳区科技计划项目“生活垃圾填埋场渗滤液高效脱氮和膜浓缩液处理关键技术开发”，15万元，负责人(2011.7-2012.6)
3. 教育部“新世纪优秀人才支持计划”项目“碳纳米管修饰电极制备及其在微生物燃料电池中的应用研究”，负责人(2011.1-2013.12)
4. 国家自然科学基金“耦合离子交换功能的高分子絮凝剂及其去除水中小分子溶解性有机物的研究”(21077001)，36万元，负责人(2011.1-2013.12)
5. 中韩(NSFC-KOSEF)合作项目“利用无机-有机复合絮凝剂强化溶气气浮和膜工艺去除中韩水源中微污染物的研究”(20911140275)，8万元，负责人(2009.6-2011.5)
6. 国家自然科学基金“共价键合型无机-有机复合高分子絮凝剂的制备、性能和形态特征”(20607001)，25万元，负责人(2007.1-2009.12)
7. “十一五”国家科技支撑计划重大项目“南水北调工程若干关键技术研究与应用”课题“丹江口水源区黄姜加工新工艺关键技术研究”(2006BAB04A14)之子课题“黄姜加工废水高效处理集成技术”，80万元，负责人(2006.12-2010.12)
8. “十一五”国家科技支撑计划重点项目“农村安全供水集成技术研究与示范”课题二“劣质地下水处理技术研究与设备研制”(2006BAD01B02)之子课题“劣质地下水处理新技术研究”，50万元，负责人(2006.10-2010.12)
9. 北京市“科技新星”计划项目“共价键合型无机-有机复合高分子絮凝剂的制备、性能和形态特征”(2007A007)，8万元，负责人(2007.12-2010.12)
10. 中国博士后科学基金项目(2004-03)“有机硅改性聚合氯化铝的制备、表征及絮凝性能研究”，负责人(2004-2005)
开发的主要技术和产品
1. 共价键型无机-有机复合絮凝剂研究组长期从事新型絮凝剂开发和应用研究，最近开发了共价键型无机－有机复合絮凝剂。这种絮凝剂是在传统金属盐絮凝剂、有机高分子絮凝剂、无机高分子絮凝剂、无机复合絮凝剂、无机－有机复合絮凝剂（这些絮凝剂主要去除胶体污染物）基础上发展而来的新一代絮凝剂。它区别于其他絮凝剂的最大特点是其无机组分和有机组分是通过硅烷偶联剂以共价键结合在一起的，因而可充分发挥无机絮凝剂和有机絮凝剂的优点。此絮凝剂不仅能高效去除其他絮凝剂可去除的胶体颗粒物、磷、氟、砷等，还可以高效去除分子量小于500的高度溶解的天然有机物（NOM）、污水有机物（EfOM）或溶解性微生物产物（SMP）、药品和个人护理品（PPCPs）、内分泌干扰物（EDCs）、持久性有机污染物（POPs）等。研究证明通过絮凝剂形态调控和结构定制可在传统絮凝理论和实践方面实现突破。
2. 固化剂以自然界中具有活性的多种天然矿物中间体制备而成，可用于水处理絮凝过程产生的污泥、疏浚污泥、工业污泥、重金属污染污泥或土壤、PCB污染污泥或土壤、焚烧灰、河道湖泊底泥等的固化。通过矿物中间体与污染物质之间发生的离子交换、吸附、分解反应以及矿物中间体之间发生的凝聚、结晶化、固溶体形成反应等达到污染物固化和稳定化的目的。固化剂采用天然矿物质原料，廉价、安全。固化过程操作简单，只需在具有一定含水率的条件下加入固化剂搅拌后养生即可。固化后污染物不易溶出，并可有效消除异味。采用该方法可对污泥或污染土壤进行原位固化或修复，也可进行异位固化，固化物可作为道路基材进行再利用。
3. 基于“絮凝－固化”的废水或膜浓缩液深度处理技术含难降解污染物的废水（如化工废水、垃圾渗滤液等）在生物处理后通常难以达标排放，采用纳滤或反渗透进一步处理可达标排放但又产生了大量难以处理的膜浓缩液。研究组开发了基于“絮凝－固化”的废水或膜浓缩液深度处理技术，利用自我研发的共价键型无机－有机复合絮凝剂和固化剂使废水或膜浓缩液达标排放。产生的污泥经半脱水固化后进企业锅炉焚烧，或完全固化、养生后作为道路基材或直接填埋。
4. 高浓度难降解有机废水处理技术高浓度难降解有机废水除了含有高浓度COD，还可能含有高浓度的对生物活性有抑制作用的物质，包括一些有毒有害的有机物、硫酸盐、氨氮、硝酸盐等。研究组开发了“改进型两相厌氧”技术，在两相厌氧中插入脱毒单元以提高厌氧过程对有机物的去除效果；开发了“零价铁生物滤池”技术，提高了难降解有机物和氮的脱除效率。通过对“改进型两相厌氧”和“零价铁生物滤池”的嵌套和优化，实现了高浓度难降解有机废水的高效处理。“改进型两相厌氧－零价铁生物滤池”工艺在南水北调中线水源区黄姜加工污染治理工程中发挥了重要作用。
5. 基于道南渗析的饮用水净化设备基于道南渗析原理，开发了分散式饮用水净化设备。该设备以电化学势差为推动力，以食盐作为唯一驱动物质，可有效去除水中砷、氟、硝酸盐和高氯酸盐等有害物质。含有砷、氟、硝酸盐或高氯酸盐的地下水经处理后各项指标均能满足生活饮水卫生标准（GB5749–2006）的要求，每升水处理费用不足0.006元。该设备避免了反渗透等传统膜技术中复杂的预处理环节以及严重的膜污染现象，具有设备简单、操作简便、成本低廉、运行稳定、易于维护、受水质影响小等优点，适于在欠发达地区推广使用。

代表性论文

1. Zhao HZ, Peng JX, Lin SS, Zhang Y. Covalently bound organic silicate aluminum hybrid coagulants: preparation, characterization and coagulation behavior. Environmental Science & Technology, 2009, 43(6): 2041-2046
2. Zhao HZ, Zhao B, Yang W, Li TH. Effects of Ca2+ and Mg2+ on defluoridation in the electrocoagulation process. Environmental Science & Technology, 2010, 44(23): 9112-9116
3. Zhao HZ, Zhang Y, Zhao B, Chang YY, Li ZS. Electrochemical reduction of carbon dioxide in an MFC-MEC system with a layer-by-layer self-assembly carbon nanotube/cobalt phthalocyanine modified electrode. Environmental Science & Technology, 2012, 46(9): 5198-5204
4. Zhao B, *Zhao HZ, Dockko S, Ni JR. Arsenate removal from simulated groundwater with a Donnan dialyzer. Journal of Hazardous Materials, 2012, 215-216: 159-165
5. Zhao HZ, Zhang Y, Chang YY, Li ZS. Conversion of a substrate carbon source to formic acid for CO2 emission reduction utilizing series-stacked microbial fuel cells. Journal of Power Sources, 2012, 217: 59-64
6. Zhao HZ, Sun JJ, Song J, Yang QZ. Direct electron transfer and conformational change of glucose oxidase on carbon nanotube-based electrodes. Carbon, 2010, 48(5): 1508-1514
7. Zhao HZ, Du Q, Li ZS, Yang QZ. Mechanisms for the direct electron transfer of cytochrome c induced by multi-walled carbon nanotubes. Sensors, 2012, 12(8): 10450-10462
8. Zhao HZ, Zhang Y, He XJ, Wang HY. Stability and coagulation behavior of solid Al13 purified with an ethanol-acetone fractional precipitation method. Chemical Engineering Journal, 2012, 179: 203-208
9. Zhao HZ, Wang HY, Dockko S, Zhang Y. The formation mechanism of Al13 and its purification with an ethanol–acetone fractional precipitation method. Separation and Purification Technology, 2011, 81(3): 466-471
10. Sun JJ, *Zhao HZ, Yang QZ, Song J, Xue A. A novel layer-by-layer self-assembled carbon nanotube-based anode: Preparation, characterization, and application in microbial fuel cell. Electrochimica Acta, 2010, 55(9): 3041-3047
11. Zhao HZ, Sun Y, Xu LN, Ni JR. Removal of Acid Orange 7 in simulated wastewater using a three-dimensional electrode reactor: Removal mechanisms and dye degradation pathway. Chemosphere, 2010, 78(1): 46-51
12. Zhao HZ, Liu C, Xu Y, Ni JR. High-concentration polyaluminum chloride: Preparation and effects of the Al concentration on the distribution and transformation of Al species. Chemical Engineering Journal, 2009, 155(1-2): 528-533
13. Zhao HZ, Peng JX, Xue A, Ni JR. Distribution and transformation of Al species in organic silicate aluminum hybrid coagulants. Composites Science and Technology, 2009, 69(10): 1629-1634
14. Zhao HZ, Yang W, Zhu J, Ni JR. Defluoridation of drinking water by combined electrocoagulation: Effects of the molar ratio of alkalinity and fluoride to Al(III). Chemosphere, 2009, 74(10): 1391-1395
15. Zhao HZ, Cheng P, Zhao B, Ni JR. Yellow ginger processing wastewater treatment by a hybrid biological process. Process Biochemistry, 2008, 43(12): 1427-1431
16. Zhao HZ, Yang HW, Guan YT, Jiang ZP. The transformation of aluminium species in the processes of coagulation, sedimentation and filtration. Water Science and Technology, 2006, 53(7): 225-233
17. Zhao B, Zhao HZ, Ni JR. Modeling of the Donnan dialysis process for arsenate removal. Chemical Engineering Journal, 2010, 160(1): 170-175
18. Zhao B, Zhao HZ, Ni JR. Arsenate removal by Donnan dialysis: Effects of the accompanying components. Separation and Purification Technology, 2010, 72(3): 250-255
19. Zhang BG, Zhou SG, Zhao HZ, Shi CH, Kong LC, Sun JJ, Yang Y, Ni JR. Factors affecting the performance of microbial fuel cells for sulfide and vanadium (V) treatment. Bioprocess and Biosystems Engineering, 2010, 33(2): 187-194
20. Zhang BG, Zhao HZ, Shi CH, Zhou SG, Ni JR. Simultaneous removal of sulfide and organics with vanadium(V) reduction in microbial fuel cells. Journal of Chemical Technology & Biotechnology, 2009, 84(12): 1780-1786
21. Zhang BG, Zhao HZ, Zhou SG, Shi CH, Wang C, Ni JR. A novel UASB–MFC–BAF integrated system for high strength molasses wastewater treatment and bioelectricity generation. Bioresource Technology, 2009, 100(23): 5687-5693
22. Cheng P, Zhao HZ, Zhao B, Ni JR. Pilot treatment of wastewater from Dioscorea zingiberensis C.H. Wright production by anaerobic digestion combined with a biological aerated filter. Bioresource Technology, 2009, 100(12): 2918-2925
23. Lai P, Zhao HZ, Zeng M, Ni JR. Study on treatment of coking wastewater by biofilm reactors combined with zero-valent iron process. Journal of Hazardous Materials, 2009, 162(2-3): 1423–1429
24. Zhu XP, Tong MP, Shi SY, Zhao HZ, Ni JR. Essential explanation of the strong mineralization performance of boron-doped diamond electrodes. Environmental Science & Technology, 2008, 42(13): 4914-4920
25. Huang W, Zhao HZ, Ni JR, Zuo H, Qiu LL, Li H, Li H. The best utilization of D-zingiberensis C.H. Wright by an eco-friendly process. Bioresource Technology, 2008, 99(15): 7407-7411
26. Lai P, Zhao HZ, Ye ZF, Ni JR. Assessing the effectiveness of treating coking effluents using anaerobic and aerobic biofilms. Process Biochemistry, 2008, 43(3): 229-237
27. Xu LN, Zhao HZ, Shi SY, Zhang GZ, Ni JR. Electrolytic treatment of Acid Orange 7 from aqueous solution by a three-dimensional electrode reactor. Dyes and Pigments, 2008, 77(1): 158-164
28. Zhu XP, Shi SY, Wei JJ, Lv FX, Zhao HZ, Kong JT, He Q, Ni JR. Electrochemical oxidation characteristics of p-substituted phenols using a boron-doped diamond electrode. Environmental Science & Technology, 2007, 41(18): 6541-6546
29. Lai P, Zhao HZ, Wang C, Ni JR. Advanced treatment of coking wastewater by coagulation and zero-valent iron processes. Journal of Hazardous Materials, 2007, 147(1-2): 232-239
30. Zhu J, Zhao HZ, Ni JR. Fluoride distribution in electrocoagulation defluoridation process. Separation and Purification Technology, 2007, 56(2),184-191
31. Wang WD, Yang HW, Zhao HZ, Jiang ZP. Transfer and Transport of Aluminum in Filtration Unit. Journal of Environmental Sciences-China, 2007, 19(8): 897-901
32. Zhao HZ, Ge XP, Luan ZK, Jiang ZP. Effects of Ca on the distribution, structure and morphology of aluminum species in polyaluminum chloride. Chinese Science Bulletin, 2004, 49(12): 1241-1244
33. Zhao HZ, Luan ZK, Jiang ZP. The influence of Ca on hydrolysisand polymerization of aluminum and physicochemical characteristics of polyaluminum chloride. Chinese Journal of Inorganic Chemistry, 2004, 20(9): 1045-1049
34. Zhao HZ, Luan ZK, Gao BY, Yue QY. Synthesis and flocculation properties of poly(diallyldimethylammonium chloride-vinyl trimethoxysilane) and poly(diallyl dimethyl ammonium chloride-acrylamide-vinyl trimethoxysilane). Journal of Applied Polymer Science, 2002, 84(2), 335-342
35. Zhao HZ, Luan ZK, Su YB, Wang SG. Purification and characterization of Al13 species, Chemical Journal of Chinese Universities-Chinese, 2002, 23: 751-755
36. 徐丽娜, 赵华章, 倪晋仁. 阴极材料对三相三维电极反应器电解处理酸性橙7的影响研究. 环境科学, 2008, 29(4): 94-99
37. 赖鹏, 赵华章, 叶正芳, 倪晋仁, 曾明. 生物滤池A/O工艺处理焦化废水研究. 环境科学, 2007, 28(12):75-81
38. 徐丽娜, 赵华章, 叶正芳, 倪晋仁. 生物-微电解组合工艺处理染料废水研究. 环境工程学报, 2007, 1 (12): 10-14
39. 赵华章, 栾兆坤, 岳钦艳, 高宝玉. PDMDAAC系列絮凝剂的脱色性能研究. 环境化学, 2002, 21(2), 149-154
40. 赵华章, 高宝玉, 岳钦艳, 于慧, 王艳. 二甲基二烯丙基氯化铵的合成及其分析. 油田化学, 2000, 17(2), 184-187

主要专利

1. 赵华章, 彭建雄, 孙娟娟. 一种共价键型无机有机复合絮凝剂、制备工艺及其应用. 授权号：CN101298347B，ZL专利号：200810115990.8
2. 赵华章, 彭建雄, 孙娟娟. 一种聚硅铝絮凝剂、制备工艺及其应用. 授权号：CN101298346B，ZL专利号：200810115989.5
3. 赵华章, 杨伟, 朱珺, 倪晋仁. 组合电絮凝除氟工艺及其应用. 授权号：CN101428879B，ZL专利号：200810240043.1
4. 赵华章, 赵斌, 倪晋仁. 同步吸附解吸的选择性膜技术的装置、方法及其应用. 授权号：CN101439889B，ZL专利号：200810240044.6
5. 赵华章, 徐子恺, 程鹏, 倪晋仁. 一种高效处理黄姜加工废水的方法及其用途, 授权号：CN1318323C，ZL专利号：200510132060.X
6. 赵华章，蒋展鹏，杨宏伟，师绍琪. 水中低浓度溶解态铝和胶体态铝的分离测定方法，授权号：CN1282875C，ZL专利号：200410042534.7
7. 徐丽娜, 赵华章, 曾明, 倪晋仁. 高盐度偶氮染料废水处理新型组合工艺. 授权号：CN100420642C，ZL专利号：200610150054.1
8. 栾兆坤，赵华章，王曙光，贾智萍，轴承打磨废水的回用处理方法，授权号：CN1137856C，ZL专利号：00133653.3
9. 栾兆坤，陈福泰，赵华章，王曙光，逆流式气浮水处理方法及其装置，授权号：CN1124984C，ZL专利号：01115476.4

Dr. Huazhang Zhao

Accosiate professor

E-mail: zhaohuazhang@pku.edu.cn

Tel: (86-10) 6275-4292-815; Fax: (86-10) 6275-6526;

College of Environmental Science and Engineering, Peking University, Beijing 100871

P. R. China

Education

July 2003

Ph. D. in Environmental Engineering, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences.

July 2000

M. S. in Environmental Engineering, College of Environmental Science and Engineering, Shandong University.

July 1995

Graduated from the Department of Environmental Engineering, China University of Petroleum.

Work Experience

2007 – Present

Associate Professor, Department of Environmental Engineering, College of Environmental Science and Engineering,Peking University.

2005 – 2007

Lecturer, Department of Environmental Engineering, College of Environmental Science and Engineering, Peking University.

2003 – 2005

Postdoctor, Department of Environmental Science and Engineering, Tsinghua University.

1995 – 1997

Head of Labouratory, Qingdao Huarun Petrochemical Co., Ltd., China.

Research Interests

(1) Physicochemical technology (chemical coagulation, electrocoagulation, zero-valent iron, etc.) to remove Fluoride, Arsenic, Phosphorus, Dissolved Organic Matters from water and wastewater.
(2) Materials for water, wastewater and sludge treatment: coagulant, flocculant, dewatering agent, demulsifier, cementation powder, etc. Developing covalently bound inorganic and organic hybrid coagulants to remove the dissolved organic matters (MW<500) from water.
(3) Novel bioelectrode and microbial-fuel-cell based water treatment process for Fluoride, Arsenic, Phosphorus, Nitrogen and CO₂(reduction and transformation) removal.
(4) Combined physicochemical and biological processes for high-strength refractory wastewater treatment.

A Brief Introduction to Teaching and Research

Dr. Huazhang Zhao has published more than 80 peer-reviewed paperssupported by the Program for New Century Excellent Talents in University of Ministry of Education of China (2010) and the Program of Beijing Nova of Science and Technology (2007). He got the P&G Teaching Award (2008) and Award for Excellent Young Teacher of Peking University (2009). He is responsible for two compulsory courses for undergraduate students (Water Treatment Engineering, Environmental Engineering Experiments) and one basic course for graduate students (Process Chemistry for Water and Wastewater Treatment). (>40 cited by SCI, >40 cited by EI, and 5 published on ES&T) and gained 9 authorized patents of invention. He has been responsible for 10 research projects granted by Ministry of Science and Technology, National Natural Science Foundation (NSFC) of China, etc. As a key investigator, he has taken part in more than 10 research projects including National 863 Project, NSFC programs. He received numerous prestigious awards such as Science and Technology Development Award by Education Ministry (2007) and by Shandong Province (2002), and Award for Excellent Scientific Researcher of Colleges and Universities (2001) of China. He was

Research Projects

1. “Carbon fixation technology for concentrated effluents from membrane process for landfill leachate treatment”- a subproject from the National Key Technology R&D Program for the 12th Five-year Plan, 2011-2014
2. “Fabrication technique for carbon nanotube modified electrode and its application in microbial fuel cell” supported by the Program for New Century Excellent Talents in University of Ministry of Education of China, 2011-2013
3. “Polymer flocculant with an ion-exchange function to remove low-molecular-weight dissolved organic matter from water” supported by the National Natural Science Foundation of China, 2011-2013
4. “Nitrogen removal and the disposal of membrane concentrates in landfill leachate treatment process” supported by Science and Technology Commission of Chaoyang District, Beijing, 2011-2012
5. “Micropollutant removal behavior using dissolved air flotation and membrane process with dosing hybrid coagulant in water source of Korea and China” supported by the NSFC-KOSEF Scientific Cooperation Program, 2009-2011
6. “Preparation, characterization and property of covalently bound inorganic and organic hybrid coagulants” supported by the National Natural Science Foundation, 2007-2009
7. “Integrated technology for high-efficient treatment of yellow ginger processing waste water”- a subproject from the National Key Technology R&D Program for the 11th Five-year Plan, 2006-2009
8. “Novel technology for the treatment of groundwater containing high-concentration F or As in rural areas”- a subproject from the National Key Technology R&D Program for the 11th Five-year Plan, 2006-2010
9. “Preparation, characterization and property of covalently bound inorganic and organic hybrid coagulants” supported by the Program of Beijing Nova of Science and Technology, 2007-2010
10. “Preparation, characterization and flocculation performance of organic silicon modified polyaluminum” supported by the Chinese Postdoctoral Science Foundation, 2004-2005

Honors and Awards

1. New Century Excellent Talent in University of Ministry of Education of China, 2010
2. P&G prize for excellent teacher, Peking University, 2008
3. Nova of Beijing Science and Technology, 2007
4. “High-concentration Ammonium Wastewater Treatment by Immobilized Microorganism”, the first-prize of Science and Technology Progress of Education, Ministry of Education, 2007
5. “High-efficient and Multi-functional Organic Polymer Flocculant”, Science and Technology Development Award, Science and Technology Development Award Committee of Shandong Province, 2002
6. “High-efficient and Multi-functional Organic Polymer Flocculant”, Award for Excellent Scientific Researcher of Colleges and Universities, Shandong Education Office, 2001

Selected Peer-Reviewed Papers

1. Zhao HZ, Peng JX, Lin SS, Zhang Y. Covalently bound organic silicate aluminum hybrid coagulants: preparation, characterization and coagulation behavior. Environmental Science & Technology, 2009, 43(6): 2041-2046
2. Zhao HZ, Zhao B, Yang W, Li TH. Effects of Ca²⁺ and Mg²⁺ on defluoridation in the electrocoagulation process. Environmental Science & Technology, 2010, 44(23): 9112-9116
3. Zhao HZ, Zhang Y, Zhao B, Chang YY, Li ZS. Electrochemical reduction of carbon dioxide in an MFC-MEC system with a layer-by-layer self-assembly carbon nanotube/cobalt phthalocyanine modified electrode. Environmental Science & Technology, 2012, 46(9): 5198-5204
4. Zhao B, *Zhao HZ, Dockko S, Ni JR. Arsenate removal from simulated groundwater with a Donnan dialyzer. Journal of Hazardous Materials, 2012, 215-216: 159-165
5. Zhao HZ, Zhang Y, Chang YY, Li ZS. Conversion of a substrate carbon source to formic acid for CO2 emission reduction utilizing series-stacked microbial fuel cells. Journal of Power Sources, 2012, 217: 59-64
6. Zhao HZ, Sun JJ, Song J, Yang QZ. Direct electron transfer and conformational change of glucose oxidase on carbon nanotube-based electrodes. Carbon, 2010, 48(5): 1508-1514
7. Zhao HZ, Du Q, Li ZS, Yang QZ. Mechanisms for the direct electron transfer of cytochrome c induced by multi-walled carbon nanotubes. Sensors, 2012, 12(8): 10450-10462
8. Zhao HZ, Zhang Y, He XJ, Wang HY. Stability and coagulation behavior of solid Al13 purified with an ethanol-acetone fractional precipitation method. Chemical Engineering Journal, 2012, 179: 203-208
9. Zhao HZ, Wang HY, Dockko S, Zhang Y. The formation mechanism of Al13 and its purification with an ethanol–acetone fractional precipitation method. Separation and Purification Technology, 2011, 81(3): 466-471
10. Sun JJ, *Zhao HZ, Yang QZ, Song J, Xue A. A novel layer-by-layer self-assembled carbon nanotube-based anode: Preparation, characterization, and application in microbial fuel cell. Electrochimica Acta, 2010, 55(9): 3041-3047
11. Zhao HZ, Sun Y, Xu LN, Ni JR. Removal of Acid Orange 7 in simulated wastewater using a three-dimensional electrode reactor: Removal mechanisms and dye degradation pathway. Chemosphere, 2010, 78(1): 46-51
12. Zhao HZ, Liu C, Xu Y, Ni JR. High-concentration polyaluminum chloride: Preparation and effects of the Al concentration on the distribution and transformation of Al species. Chemical Engineering Journal, 2009, 155(1-2): 528-533
13. Zhao HZ, Peng JX, Xue A, Ni JR. Distribution and transformation of Al species in organic silicate aluminum hybrid coagulants. Composites Science and Technology, 2009, 69(10): 1629-1634
14. Zhao HZ, Yang W, Zhu J, Ni JR. Defluoridation of drinking water by combined electrocoagulation: Effects of the molar ratio of alkalinity and fluoride to Al(III). Chemosphere, 2009, 74(10): 1391-1395
15. Zhao HZ, Cheng P, Zhao B, Ni JR. Yellow ginger processing wastewater treatment by a hybrid biological process. Process Biochemistry, 2008, 43(12): 1427-1431
16. Zhao HZ, Yang HW, Guan YT, Jiang ZP. The transformation of aluminium species in the processes of coagulation, sedimentation and filtration. Water Science and Technology, 2006, 53(7): 225-233
17. Zhao B, Zhao HZ, Ni JR. Modeling of the Donnan dialysis process for arsenate removal. Chemical Engineering Journal, 2010, 160(1): 170-175
18. Zhao B, Zhao HZ, Ni JR. Arsenate removal by Donnan dialysis: Effects of the accompanying components. Separation and Purification Technology, 2010, 72(3): 250-255
19. Zhang BG, Zhou SG, Zhao HZ, Shi CH, Kong LC, Sun JJ, Yang Y, Ni JR. Factors affecting the performance of microbial fuel cells for sulfide and vanadium (V) treatment. Bioprocess and Biosystems Engineering, 2010, 33(2): 187-194
20. Zhang BG, Zhao HZ, Shi CH, Zhou SG, Ni JR. Simultaneous removal of sulfide and organics with vanadium(V) reduction in microbial fuel cells. Journal of Chemical Technology & Biotechnology, 2009, 84(12): 1780-1786
21. Zhang BG, Zhao HZ, Zhou SG, Shi CH, Wang C, Ni JR. A novel UASB–MFC–BAF integrated system for high strength molasses wastewater treatment and bioelectricity generation. Bioresource Technology, 2009, 100(23): 5687-5693
22. Cheng P, Zhao HZ, Zhao B, Ni JR. Pilot treatment of wastewater from Dioscorea zingiberensis C.H. Wright production by anaerobic digestion combined with a biological aerated filter. Bioresource Technology, 2009, 100(12): 2918-2925
23. Lai P, Zhao HZ, Zeng M, Ni JR. Study on treatment of coking wastewater by biofilm reactors combined with zero-valent iron process. Journal of Hazardous Materials, 2009, 162(2-3): 1423–1429
24. Zhu XP, Tong MP, Shi SY, Zhao HZ, Ni JR. Essential explanation of the strong mineralization performance of boron-doped diamond electrodes. Environmental Science & Technology, 2008, 42(13): 4914-4920
25. Huang W, Zhao HZ, Ni JR, Zuo H, Qiu LL, Li H, Li H. The best utilization of D-zingiberensis C.H. Wright by an eco-friendly process. Bioresource Technology, 2008, 99(15): 7407-7411
26. Lai P, Zhao HZ, Ye ZF, Ni JR. Assessing the effectiveness of treating coking effluents using anaerobic and aerobic biofilms. Process Biochemistry, 2008, 43(3): 229-237
27. Xu LN, Zhao HZ, Shi SY, Zhang GZ, Ni JR. Electrolytic treatment of Acid Orange 7 from aqueous solution by a three-dimensional electrode reactor. Dyes and Pigments, 2008, 77(1): 158-164
28. Zhu XP, Shi SY, Wei JJ, Lv FX, Zhao HZ, Kong JT, He Q, Ni JR. Electrochemical oxidation characteristics of p-substituted phenols using a boron-doped diamond electrode. Environmental Science & Technology, 2007, 41(18): 6541-6546
29. Lai P, Zhao HZ, Wang C, Ni JR. Advanced treatment of coking wastewater by coagulation and zero-valent iron processes. Journal of Hazardous Materials, 2007, 147(1-2): 232-239
30. Zhu J, Zhao HZ, Ni JR. Fluoride distribution in electrocoagulation defluoridation process. Separation and Purification Technology, 2007, 56(2),184-191
31. Wang WD, Yang HW, Zhao HZ, Jiang ZP. Transfer and Transport of Aluminum in Filtration Unit. Journal of Environmental Sciences-China, 2007, 19(8): 897-901
32. Zhao HZ, Ge XP, Luan ZK, Jiang ZP. Effects of Ca on the distribution, structure and morphology of aluminum species in polyaluminum chloride. Chinese Science Bulletin, 2004, 49(12): 1241-1244
33. Zhao HZ, Luan ZK, Jiang ZP. The influence of Ca on hydrolysisand polymerization of aluminum and physicochemical characteristics of polyaluminum chloride. Chinese Journal of Inorganic Chemistry, 2004, 20(9): 1045-1049
34. Zhao HZ, Luan ZK, Gao BY, Yue QY. Synthesis and flocculation properties of poly(diallyldimethylammonium chloride-vinyl trimethoxysilane) and poly(diallyl dimethyl ammonium chloride-acrylamide-vinyl trimethoxysilane). Journal of Applied Polymer Science, 2002, 84(2), 335-342
35. Zhao HZ, Luan ZK, Su YB, Wang SG. Purification and characterization of Al13 species, Chemical Journal of Chinese Universities-Chinese, 2002, 23: 751-755

Conference Papers

1. Zhao HZ, Sun JJ, Shi G. Vertically aligned carbon nanotube arrays assembled on glassy carbon electrode, Nanotechnology 2010: Advanced Materials, CNTs, Particles, Films and Composites - 2010 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2010, pp 270-273, 2010/6/21
2. Zhao HZ, Zhao B. Arsenate Removal from Simulated Groundwater by Donnan Dialysis. 5th International Conference on Environmental Science and Technology (ICEST2010), Houston, USA, July 12-16, 2010
3. Zhao HZ. High-Efficiency Al-based Coagulant and the Distribution and Transformation of Al Species. Water resources management and drinking water quality control, Program for the Sino-Swiss and technology cooperation workshop, Harbin Institute of Technology, China, January 22-24, 2008
4. Zhao HZ, Cheng P, Zhao B, Ni JR. Performance of a hybrid process based on two-phase anaerobic digestion and biological aerated filter for yellow ginger processing wastewater treatment. Proceedings of 4th IWA Specialist Conference on Efficient USE and Management of Urban Water Supply, Jeju, Korea, May 20-23, 2007
5. Zhao HZ, Yang HW, Guan YT, Jiang ZP. The transformation of aluminum species in the processes of coagulation, sedimentation, and filtration. Proceedings of IWA International Conference on Particle Separation 2005, Seoul, Korea, June 1-3, 2005

Authorized Patents of Invention

1. Huazhang Zhao, Jianxiong Peng, Juanjuan Sun, a method for preparation of covalently bound inorganic-organic flocculants, Patent Number: ZL 200810115990.8
2. Huazhang Zhao, Jianxiong Peng, Juanjuan Sun, the preparation process and application of organic silicate aluminum hybrid flocculants, Patent Number: ZL 200810115989.5
3. Huazhang Zhao, Wei Yang, Jinren Ni, Combined electrocoagulation process for defluoridation and its application, Patent Number: ZL 200810240043.1
4. Huazhang Zhao, Bin Zhao, Jinren Ni, The selective membrane for synchronous adsorption and desorption: apparatus, method, and application, Patent Number: ZL 200810240044.6
5. Huazhang Zhao, Zikai Xu, Peng Chen, Jinren Ni, a method for high-efficient treatment of yellow ginger processing waste water, Patent Number: ZL 200510132060.X
6. Huazhang Zhao, Zhanpeng Jiang, Hongwei Yang, Shaoqi Shi, a method for separation and determination of low concentration dissolved/colloid aluminum in water, Patent Number: ZL 200410042534.7
7. Zhaokun Luan, Huazhang Zhao, Shuguang Wang, Zhiping Jia. a method to reuse the wastewater from bearing production, Patent Number ZL: 00133653.3
8. Zhaokun Luan, Futai Chen, Huazhang Zhao, Shuguang Wang, countercurrent style dissolved air flotation (DAF) device and its application in water treatment, Patent Number: ZL 01115476.4
9. Lina Xu, Huazhang Zhao, Ming Zeng, Jinren Ni, a new integrated process for high salinity azo-dyes wastewater treatment, Patent Number: ZL 200610150054.1

朱永官院士朱永	邱顺添--天津大学环境
章林伟 --中国城镇供水	油新华--副总工程师，
谭春，高级工程师，毕	周艳莉，工学硕士，毕
王浩正中国市政工程华	郑兴灿-中国市政工程华
杰夫·格林（Jeff Gre	王淼 ----哈尔滨市多相
张春敏----中国市政工	李成江--中国市政工程
张悦--住房和城乡建设

赵华章---北京大学 环境工程系 副教授

赵华章---北京大学环境工程系副教授